{"id":70282,"date":"2026-01-08T19:38:55","date_gmt":"2026-01-09T01:38:55","guid":{"rendered":"https:\/\/www.arbin.com\/?p=70282"},"modified":"2026-02-05T18:41:47","modified_gmt":"2026-02-06T00:41:47","slug":"accuracy-and-precision-impact-of-battery-testers-accuracy","status":"publish","type":"post","link":"https:\/\/www.arbin.com\/zh\/accuracy-and-precision-impact-of-battery-testers-accuracy.html","title":{"rendered":"Accuracy and Precision: Impact of battery tester&#8217;s accuracy"},"content":{"rendered":"<p data-renderer-start-pos=\"1\" data-local-id=\"cd393932-e556-4f29-87f3-51141c20b730\"><strong>In the previous article, we introduced the <a href=\"https:\/\/www.arbin.com\/zh\/accuracy-and-precision-overview.html\/\">concepts of accuracy and precision<\/a>, along with a brief overview of their influence on battery testing. In this article, we will take a deeper look at the impact of accuracy.<\/strong><\/p>\n<p data-renderer-start-pos=\"219\" data-local-id=\"222f5c53-9198-4de5-8918-c94ed98eb7c9\">We will take an example about the impact on capacity measurement and Coulombic Efficiency measurement.<\/p>\n<p data-renderer-start-pos=\"323\" data-local-id=\"a1b0a32a-2d00-44ed-b08d-92b74762a526\">As we all know, Common Procedure for Measuring Coulombic Efficiency (according to <span data-highlighted=\"true\" data-vc=\"highlighted-text\"><span class=\"_kqswh2mm\"><span class=\"_5pioz8co _189e1dm9 _1il9buyh _19lc184f _d0altlke\" data-testid=\"definition-highlighter\">IEC<\/span><\/span><\/span> practices and typical laboratory methods) is:<\/p>\n<ol class=\"ak-ol\" start=\"1\" data-local-id=\"93add6e4-dd7e-426a-97b0-95ad8604eed0\" data-indent-level=\"1\">\n<li>\n<p data-renderer-start-pos=\"458\" data-local-id=\"a60a65f2-a6a7-45a2-a279-85ee645fcf62\"><strong data-renderer-mark=\"true\">Charge the cell<\/strong> (usually using a CC\u2013CV protocol) and record the charged capacity Qcharge<\/p>\n<\/li>\n<li>\n<p data-renderer-start-pos=\"550\" data-local-id=\"c216371b-d793-4bab-873e-091872126d40\"><strong data-renderer-mark=\"true\">Discharge the cell<\/strong> (typically using constant-current to a specified cutoff voltage) to obtain the discharged capacity Qdischarge<\/p>\n<\/li>\n<li>\n<p data-renderer-start-pos=\"682\" data-local-id=\"27682fb7-a9e9-49f6-b841-958459912e57\"><strong data-renderer-mark=\"true\">Calculate the ratio Qdischarge\/Qcharge\u200b<\/strong> to determine the Coulombic Efficiency for that cycle.<\/p>\n<\/li>\n<\/ol>\n<div class=\"rich-media-item mediaSingleView-content-wrap image-center css-1hl6l0l\" data-layout=\"center\" data-width=\"306\" data-width-type=\"pixel\" data-node-type=\"mediaSingle\" data-vc=\"media-single\" data-renderer-start-pos=\"781\" data-media-vc-wrapper=\"true\" data-ssr-placeholder=\"Eb7Gh:EfLS5:z8NN7:qz-Pe:Y6119-0\">\n<div class=\"css-k0arin\">\n<div data-type=\"file\" data-node-type=\"media\" data-width=\"228\" data-height=\"70\" data-id=\"92bc1020-fe4d-40ae-bfdf-67d78b364867\" data-collection=\"contentId-1038254255\" data-file-name=\"image-20251204-091030.png\" data-file-size=\"7080\" data-file-mime-type=\"image\/png\" data-alt=\"image-20251204-091030.png\" data-renderer-start-pos=\"782\" data-local-id=\"52b02a2a-28e9-4903-a5ee-eebf585286a4\" data-ssr-placeholder-ignored=\"\" data-context-id=\"1038254255\">\n<div id=\"newFileExperienceWrapper\" class=\"_2rkofajl _vchhusvi _kqswh2mm _ect41gqc _p12f1osq _c71l1osq _1bsb1qmm _4t3ine4n _1hlmd0i9 _1rquusvi _eg541i5c _mts3kb7n _1ntskb7n _yfmhtlke _5sb1v00u new-file-experience-wrapper\" data-testid=\"media-card-view\" data-media-vc-wrapper=\"true\" data-ssr-placeholder-ignored=\"\">\n<div class=\"_1reo15vq _18m915vq _2rkofajl _1e0c1txw _kqswh2mm _p12f1osq _1bsb1osq _4t3i1osq _c71l1osq media-file-card-view\" data-testid=\"media-file-card-view\" data-test-status=\"complete\" data-test-source=\"ssr-server\" data-cursor=\"pointer\" data-ssr-placeholder-ignored=\"\" data-test-media-name=\"image-20251204-091030.png\" data-test-progress=\"1\">\n<div class=\"_kqswstnw _1bsb1osq _4t3i1osq _1e0c1txw _2lx21bp4 _1bah1h6o _4cvr1h6o\" data-testid=\"ImageRendererWrapper\" data-ssr-placeholder-ignored=\"\">\n<p><img decoding=\"async\" class=\"size-full wp-image-70285\" src=\"https:\/\/www.arbin.com\/wp-content\/uploads\/2026\/01\/accuracy-and-precision.webp\" alt=\"accuracy and precision\" width=\"342\" height=\"105\" srcset=\"https:\/\/www.arbin.com\/wp-content\/uploads\/2026\/01\/accuracy-and-precision.webp 342w, https:\/\/www.arbin.com\/wp-content\/uploads\/2026\/01\/accuracy-and-precision-18x6.webp 18w\" sizes=\"(max-width: 342px) 100vw, 342px\" \/><\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n<p data-renderer-start-pos=\"786\" data-local-id=\"64c2e172-5cd6-4b3c-aa21-7b95c3da28d3\">Therefore, the issue of measuring Coulombic Efficiency is reduced to the issue of measuring Capacity.<\/p>\n<p data-renderer-start-pos=\"889\" data-local-id=\"50c15367-93d8-4036-86f2-c6abe7d6c3e3\">Measuring charge capacity is inherently more complex because the charging process consists of two distinct stages: a constant-current (CC) interval followed by a constant-voltage (CV) interval. During the CC stage, accurate current measurement is essential, as the charge capacity is obtained by integrating the current over the time required to raise the cell voltage from its lower limit to the upper limit (for example, from 2.5 V to 4.2 V).<\/p>\n<p data-renderer-start-pos=\"1335\" data-local-id=\"d20485a6-e3fb-48b9-b607-fc42544d14d2\">Equally important is voltage-measurement accuracy, which determines the exact moment the cell reaches the specified cutoff voltage. If the voltage reading is inaccurate, the system may prematurely terminate charging or continue charging past the intended cutoff. Either scenario results in a deviation from the true charge capacity, leading to a significant measurement error.<\/p>\n<p data-renderer-start-pos=\"1713\" data-local-id=\"32aed26a-bfb3-43b5-9c0d-f98742be4680\">Voltage-measurement accuracy becomes even more critical during the CV period, where the voltage must be held constant at the specified cutoff. This is due to some reason as follows:<\/p>\n<p data-renderer-start-pos=\"1896\" data-local-id=\"2fe6ba9c-a90b-45bd-be1c-f05781c539aa\">1.<strong data-renderer-mark=\"true\"> CV control relies entirely on accurate voltage feedback<\/strong><\/p>\n<div class=\"fabric-editor-block-mark fabric-editor-indentation-mark\" data-level=\"1\">\n<p data-renderer-start-pos=\"1956\" data-local-id=\"e4de7a77-e15f-44df-b78d-22ad22b7fc44\">During the constant-voltage stage, the cycler\u2019s goal is to maintain the cell exactly at the upper cutoff (e.g., 4.20 V). The controller continuously adjusts the current based solely on the <strong data-renderer-mark=\"true\">measured<\/strong> voltage. Any offset or drift in voltage measurement directly leads to incorrect current output.<\/p>\n<\/div>\n<ul class=\"ak-ul\" data-local-id=\"4e7bd54b-c2d6-4dab-b086-405e506a64b6\" data-indent-level=\"1\">\n<li>\n<p data-renderer-start-pos=\"2253\" data-local-id=\"438d3d19-961b-4b6f-b51f-edd55430ff7b\">If the measured voltage is <strong data-renderer-mark=\"true\">too low<\/strong>, the cycler believes the cell has not reached the cutoff \u2192 it increases the charging current unnecessarily.<\/p>\n<\/li>\n<li>\n<p data-renderer-start-pos=\"2399\" data-local-id=\"442a3248-f47a-4db1-ac79-3e32bebfce3c\">If the measured voltage is <strong data-renderer-mark=\"true\">too high<\/strong>, the cycler prematurely reduces the current.<\/p>\n<\/li>\n<\/ul>\n<div class=\"fabric-editor-block-mark fabric-editor-indentation-mark\" data-level=\"1\">\n<p data-renderer-start-pos=\"2483\" data-local-id=\"3f1c05a3-196c-4536-9455-36e47573532d\">This mismatch can lead to:<\/p>\n<\/div>\n<ul class=\"ak-ul\" data-local-id=\"a45de9b7-9faa-44fa-9566-ee41c5fdd03b\" data-indent-level=\"1\">\n<li>\n<p data-renderer-start-pos=\"2513\" data-local-id=\"5005d6cd-71d2-4efa-a268-7bd05227a05e\">unpredictable current behavior<\/p>\n<\/li>\n<li>\n<p data-renderer-start-pos=\"2547\" data-local-id=\"4f0319df-575e-4fa8-8097-8ae2c34b9ca3\">incorrect taper patterns<\/p>\n<\/li>\n<li>\n<p data-renderer-start-pos=\"2575\" data-local-id=\"28847968-5b67-4ab8-be54-3eed1fd64719\">oscillation or fluctuation of charging current<\/p>\n<\/li>\n<\/ul>\n<ol class=\"ak-ol\" start=\"2\" data-local-id=\"5b58ca57-25bc-4cd9-b914-85bf3a2730d5\" data-indent-level=\"1\">\n<li>\n<p data-renderer-start-pos=\"2627\" data-local-id=\"0b04b528-b167-41de-ac55-8f51ce711b5d\"><strong data-renderer-mark=\"true\">Severe over-measurement can trigger negative current<\/strong><\/p>\n<\/li>\n<\/ol>\n<div class=\"fabric-editor-block-mark fabric-editor-indentation-mark\" data-level=\"1\">\n<p data-renderer-start-pos=\"2683\" data-local-id=\"05ea4e2a-45e2-400f-a822-6f3599966b36\">If voltage is <strong data-renderer-mark=\"true\">substantially over-measured<\/strong> (e.g., sensing 4.25 V when actual is 4.20 V), the controller thinks the cell is \u201cover-voltage.\u201d The control algorithm may respond by issuing <strong data-renderer-mark=\"true\">negative current<\/strong> (a slight discharge) to bring the \u201cmeasured\u201d voltage back down. This negative current will be interpreted as <strong data-renderer-mark=\"true\">discharge capacity<\/strong>.<\/p>\n<\/div>\n<div class=\"fabric-editor-block-mark fabric-editor-indentation-mark\" data-level=\"1\">\n<p data-renderer-start-pos=\"3015\" data-local-id=\"062d7f38-b475-4709-a559-71cc003d4a5b\">If this occurs for even part of the CV duration, the system can log positive discharge capacity within a charge step, and also underestimate the charge capacity. This is one of the most serious consequences of voltage-measurement inaccuracy.<\/p>\n<\/div>\n<p data-renderer-start-pos=\"3258\" data-local-id=\"9b367f6e-d262-4533-9009-d9dc732b6adf\">\u963f\u5c14\u5bbe\u7684 <span data-highlighted=\"true\" data-vc=\"highlighted-text\"><span class=\"_kqswh2mm\"><span class=\"_5pioz8co _189e1dm9 _1il9buyh _19lc184f _d0altlke\" data-testid=\"definition-highlighter\">LBT\u7cfb\u5217<\/span><\/span><\/span> series, with a voltage accuracy of \u00b10.02% <span data-highlighted=\"true\" data-vc=\"highlighted-text\"><span class=\"_kqswh2mm\"><span class=\"_5pioz8co _189e1dm9 _1il9buyh _19lc184f _d0altlke\" data-testid=\"definition-highlighter\">FSR<\/span><\/span><\/span>, and especially the <span data-highlighted=\"true\" data-vc=\"highlighted-text\"><span class=\"_kqswh2mm\"><span class=\"_5pioz8co _189e1dm9 _1il9buyh _19lc184f _d0altlke\" data-testid=\"definition-highlighter\">HPS<\/span><\/span><\/span> series\u2014featuring 480 \u00b5V voltage accuracy and six current ranges with a highest accuracy of 8 nA\u2014are excellent choices for researchers who requires high accuracy and high precision battery testing.<\/p>\n<p data-renderer-start-pos=\"3538\" data-local-id=\"885fe4f4-a254-4e0e-8b4d-1d1a46e119ee\"><strong data-renderer-mark=\"true\">References<\/strong>:<\/p>\n<p data-renderer-start-pos=\"3551\" data-local-id=\"694bb228-fe59-41ec-96cb-9b3e7f77feaf\">Arbin Instruments. (2021). <em data-renderer-mark=\"true\">Battery test system accuracy and calibration white paper.<\/em> College Station, TX: Arbin Instruments.<\/p>\n<p data-renderer-start-pos=\"3677\" data-local-id=\"ff9afe22-9bdc-4c24-8ea7-c42b92c3ca3d\">Arbin Instruments. (2023). <em data-renderer-mark=\"true\"><span data-highlighted=\"true\" data-vc=\"highlighted-text\">LBT\u7cfb\u5217<\/span> Series product manual (Rev. 2.3).<\/em> College Station, TX: Arbin Instruments.<\/p>\n<p data-renderer-start-pos=\"3783\" data-local-id=\"1b771fc7-7585-47f8-a9ae-c7e41276d7f7\"><span data-highlighted=\"true\" data-vc=\"highlighted-text\"><span class=\"_kqswh2mm\"><span class=\"_5pioz8co _189e1dm9 _1il9buyh _19lc184f _d0altlke\" data-testid=\"definition-highlighter\">ASTM<\/span><\/span><\/span> International. (2020). <em data-renderer-mark=\"true\"><span data-highlighted=\"true\" data-vc=\"highlighted-text\">ASTM<\/span> E177-20: Standard practice for use of the terms precision and bias in <span data-highlighted=\"true\" data-vc=\"highlighted-text\">ASTM<\/span> test methods.<\/em> West Conshohocken, PA: <span data-highlighted=\"true\" data-vc=\"highlighted-text\">ASTM<\/span> International. <span data-inline-card=\"true\" data-card-url=\"https:\/\/doi.org\/10.1520\/E0177-20\" data-annotation-inline-node=\"true\" data-renderer-start-pos=\"3948\" data-annotation-mark=\"true\" data-ssr-placeholder=\"0vDZ-:EfLS5:z8NN7:qz-Pe:Y6119-0\"><span class=\"loader-wrapper\"><span class=\"hover-card-trigger-wrapper\" data-testid=\"hover-card-trigger-wrapper\"><a class=\"_1yt4x7n9 _2rko12b0 _v56415x0 _1e0c1nu9 _16d9qvcn _syaz13af _1rkwglyw _4cvx1w55 _19itia51 _bfhkhp5a _1a3b1r31 _4fprglyw _5goinqa1 _9oik1r31 _1bnxglyw _jf4cnqa1 _1nrm1r31 _c2waglyw _1iohnqa1 _uizt1kdv _nt751r31 _49pcglyw _1hvw1o36 _1372tlke _7ehiw5lj _1j5pglyw _1di615s3\" tabindex=\"0\" role=\"button\" href=\"https:\/\/doi.org\/10.1520\/E0177-20\" data-testid=\"inline-card-resolved-view\"><span class=\"_19itglyw _vchhusvi _r06hglyw _o5721jtm _1nmz9jpi _16d9qvcn _ca0qv77o _u5f31b66 _n3tdv77o _19bv1b66\" data-testid=\"inline-card-icon-and-title\"><span class=\"_19itglyw _vchhusvi _r06hglyw\">Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods<\/span><\/span><\/a><\/span><\/span><\/span><\/p>\n<p data-renderer-start-pos=\"3952\" data-local-id=\"fbaff291-e4bc-49b5-9ed1-7542fc936957\"><span data-highlighted=\"true\" data-vc=\"highlighted-text\">IEC<\/span>. (2018). <em data-renderer-mark=\"true\"><span data-highlighted=\"true\" data-vc=\"highlighted-text\">IEC<\/span> 62660-1:2018 \u2013 Secondary lithium-ion cells for the propulsion of electric road vehicles \u2013 Part 1: Performance testing.<\/em> Geneva, Switzerland: International Electrotechnical Commission.<\/p>\n<p data-renderer-start-pos=\"4153\" data-local-id=\"c6d9e7fa-5086-4cb2-8d8d-9892f00de723\">Newman, J., &amp; Thomas-Alyea, K. E. (2004). <em data-renderer-mark=\"true\">Electrochemical systems<\/em> (3rd ed.). Hoboken, NJ: Wiley-Interscience.<\/p>\n<h6 id=\"Case-Study:-How-Voltage-Precision-Affects-dV\/dt-and-dQ\/dV-Calculation-in-Battery-Analyzers\" data-local-id=\"b46ba99b-9a4b-4192-870a-72b04c82f5a8\" data-renderer-start-pos=\"2376\"><a href=\"https:\/\/www.arbin.com\/zh\/accuracy-and-precision-impact-of-precision.html\/\">Case Study: How Voltage Precision Affects dV\/dt and dQ\/dV Calculation in Battery Analyzers<\/a><\/h6>","protected":false},"excerpt":{"rendered":"<p>In the previous article, we introduced the concepts of accuracy and precision, along with a brief overview of their influence on battery testing. In this article, we will take a deeper look at the impact of accuracy. We will take an example about the impact on capacity measurement and Coulombic Efficiency measurement. As we all [&hellip;]<\/p>","protected":false},"author":6,"featured_media":71025,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_seopress_robots_primary_cat":"none","_seopress_titles_title":"","_seopress_titles_desc":"","_seopress_robots_index":"","inline_featured_image":false,"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"default","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"set","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[412],"tags":[109],"class_list":["post-70282","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-application-notes","tag-precision"],"acf":[],"_links":{"self":[{"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/posts\/70282","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/users\/6"}],"replies":[{"embeddable":true,"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/comments?post=70282"}],"version-history":[{"count":5,"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/posts\/70282\/revisions"}],"predecessor-version":[{"id":74923,"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/posts\/70282\/revisions\/74923"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/media\/71025"}],"wp:attachment":[{"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/media?parent=70282"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/categories?post=70282"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.arbin.com\/zh\/wp-json\/wp\/v2\/tags?post=70282"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}